No, it's not Photoshop. This is real and oh so fascinating.
This "Hole In the Face' makeup is inspired by Salvador Dali's Bronze Sculpture, Surrealist Newton.
If you look close enough, you can see her eyes, nose and mouth.
And it's not the only Dali inspired makeup application. She also had success in creating a melting face, much like the melting clock.
She also has other applications that didn't spawn from Dali.